الوزن الذري القياسي

Example: copper in terrestrial sources. Two isotopes are present: copper-63 (62.9) and copper-65 (64.9), in abundances 69% + 31%. The standard atomic weight (Ar°(Cu)) for copper is the average, weighted by their natural abundance, and then divided by the atomic mass constant mu.[1]

الوزن الذري العياري of a chemical element (symbol Ar°(E) for element "E") is the weighted arithmetic mean of the relative isotopic masses of all isotopes of that element weighted by each isotope's abundance on Earth. For example, isotope 63Cu (Ar = 62.929) constitutes 69% of the copper on Earth, the rest being 65Cu (Ar = 64.927), so

Because relative isotopic masses are dimensionless quantities, this weighted mean is also dimensionless. It can be converted into a measure of mass (with dimension قالب:Dimanalysis) by multiplying it with the dalton, also known as the atomic mass constant.

Among various variants of the notion of atomic weight (Ar, also known as relative atomic mass) used by scientists, the standard atomic weight (Ar°) is the most common and practical. The standard atomic weight of each chemical element is determined and published by the Commission on Isotopic Abundances and Atomic Weights (CIAAW) of the International Union of Pure and Applied Chemistry (IUPAC) based on natural, stable, terrestrial sources of the element. The definition specifies the use of samples from many representative sources from the Earth, so that the value can widely be used as "the" atomic weight for substances as they are encountered in reality—for example, in pharmaceuticals and scientific research. Non-standardized atomic weights of an element are specific to sources and samples, such as the atomic weight of carbon in a particular bone from a particular archeological site. Standard atomic weight averages such values to the range of atomic weights that a chemist might expect to derive from many random samples from Earth. This range is the rationale for the interval notation given for some standard atomic weight values.

Of the 118 known chemical elements, 80 have stable isotopes and 84 have this Earth-environment based value. Typically, such a value is, for example helium: Ar°(He) = 4.002602(2). The "(2)" indicates the uncertainty in the last digit shown, to read 4.002602±0.000002. IUPAC also publishes abridged values, rounded to five significant figures. For helium, Ar, abridged°(He) = 4.0026.

For fourteen elements the samples diverge on this value, because their sample sources have had a different decay history. For example, thallium (Tl) in sedimentary rocks has a different isotopic composition than in igneous rocks and volcanic gases. For these elements, the standard atomic weight is noted as an interval: Ar°(Tl) = [204.38, 204.39]. With such an interval, for less demanding situations, IUPAC also publishes a conventional value. For thallium, Ar, conventional°(Tl) = 204.38.

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التعريف

Excerpt of an IUPAC Periodic Table showing the interval notation of the standard atomic weights of boron, carbon, and nitrogen (Chemistry International, IUPAC). Example: the pie chart for boron shows it to be composed of about 20% 10B and 80% 11B. This isotope mix causes the atomic weight of ordinary Earthly boron samples to be expected to fall within the interval 10.806 to 10.821. and this interval is the standard atomic weight. Boron samples from unusual sources, particularly non-terrestrial sources, might have measured atomic weights that fall outside this range. Atomic weight and relative atomic mass are synonyms.

The standard atomic weight is a special value of the relative atomic mass. It is defined as the "recommended values" of relative atomic masses of sources in the local environment of the Earth's crust and atmosphere as determined by the IUPAC Commission on Atomic Weights and Isotopic Abundances (CIAAW).[2] In general, values from different sources are subject to natural variation due to a different radioactive history of sources. Thus, standard atomic weights are an expectation range of atomic weights from a range of samples or sources. By limiting the sources to terrestrial origin only, the CIAAW-determined values have less variance, and are a more precise value for relative atomic masses (atomic weights) actually found and used in worldly materials.

The CIAAW-published values are used and sometimes lawfully required in mass calculations. The values have an uncertainty (noted in brackets), or are an expectation interval (see example in illustration immediately above). This uncertainty reflects natural variability in isotopic distribution for an element, rather than uncertainty in measurement (which is much smaller with quality instruments).[3]

Although there is an attempt to cover the range of variability on Earth with standard atomic weight figures, there are known cases of mineral samples which contain elements with atomic weights that are outliers from the standard atomic weight range.[2]

For synthetic elements the isotope formed depends on the means of synthesis, so the concept of natural isotope abundance has no meaning. Therefore, for synthetic elements the total nucleon count of the most stable isotope (i.e., the isotope with the longest half-life) is listed in brackets, in place of the standard atomic weight.

When the term "atomic weight" is used in chemistry, usually it is the more specific standard atomic weight that is implied. It is standard atomic weights that are used in periodic tables and many standard references in ordinary terrestrial chemistry.

Lithium represents a unique case where the natural abundances of the isotopes have in some cases been found to have been perturbed by human isotopic separation activities to the point of affecting the uncertainty in its standard atomic weight, even in samples obtained from natural sources, such as rivers.[بحاجة لمصدر][محل شك]


التعريف الأرضي

An example of why "conventional terrestrial sources" must be specified in giving standard atomic weight values is the element argon. Between locations in the Solar System, the atomic weight of argon varies as much as 10%, due to extreme variance in isotopic composition. Where the major source of argon is the decay of 40 K in rocks, 40 Ar will be the dominant isotope. Such locations include the planets Mercury and Mars, and the moon Titan. On Earth, the ratios of the three isotopes 36Ar : 38Ar : 40Ar are approximately 5 : 1 : 1600, giving terrestrial argon a standard atomic weight of 39.948(1).

However, such is not the case in the rest of the universe. Argon produced directly, by stellar nucleosynthesis, is dominated by the alpha-process nuclide 36 Ar. Correspondingly, solar argon contains 84.6% 36 Ar (according to solar wind measurements),[4] and the ratio of the three isotopes 36Ar : 38Ar : 40Ar in the atmospheres of the outer planets is 8400 : 1600 : 1.[5] The atomic weight of argon in the Sun and most of the universe, therefore, would be only approximately 36.3.[6]

مسببات عدم اليقين على الأرض

Famously, the published atomic weight value comes with an uncertainty. This uncertainty (and related: precision) follows from its definition, the source being "terrestrial and stable". Systematic causes for uncertainty are:

  1. Measurement limits. As always, the physical measurement is never finite. There is always more detail to be found and read. This applies to every single, pure isotope found. For example, today the mass of the main natural fluorine isotope (fluorine-19) can be measured to the accuracy of eleven decimal places: 18.998403163(6). But a still more precise measurement system could become available, producing more decimals.
  2. Imperfect mixtures of isotopes. In the samples taken and measured the mix (relative abundance) of those isotopes may vary. For example, copper. While in general its two isotopes make out 69.15% and 30.85% each of all copper found, the natural sample being measured can have had an incomplete 'stirring' and so the percentages are different. The precision is improved by measuring more samples of course, but there remains this cause of uncertainty. (Example: lead samples vary so much, it can not be noted more precise than four figures: 207.2)
  3. Earthly sources with a different history. A source is the greater area being researched, for example 'ocean water' or 'volcanic rock' (as opposed to a 'sample': the single heap of material being investigated). It appears that some elements have a different isotopic mix per source. For example, thallium in igneous rock has more lighter isotopes, while in sedimentary rock it has more heavy isotopes. There is no Earthly mean number. These elements show the interval notation: Ar°(Tl) = [204.38204.39]. For practical reasons, a simplified 'conventional' number is published too (for Tl: 204.38).

These three uncertainties are accumulative. The published value is a result of all these.

تحديد الكتلة الذرية النسبية

Modern relative atomic masses (a term specific to a given element sample) are calculated from measured values of atomic mass (for each nuclide) and isotopic composition of a sample. Highly accurate atomic masses are available[7][8] for virtually all non-radioactive nuclides, but isotopic compositions are both harder to measure to high precision and more subject to variation between samples.[9][10] For this reason, the relative atomic masses of the 22 mononuclidic elements (which are the same as the isotopic masses for each of the single naturally occurring nuclides of these elements) are known to especially high accuracy.

النظير Atomic mass[8] Abundance[9]
المعيار النطاق
28Si 27.976 926 532 46(194) 92.2297(7)% 92.21–92.25%
29Si 28.976 494 700(22) 4.6832(5)% 4.67–4.69%
30Si 29.973 770 171(32) 3.0872(5)% 3.08–3.10%

The calculation is exemplified for silicon, whose relative atomic mass is especially important in metrology. Silicon exists in nature as a mixture of three isotopes: 28Si, 29Si and 30Si. The atomic masses of these nuclides are known to a precision of one part in 14 billion for 28Si and about one part in one billion for the others. However the range of natural abundance for the isotopes is such that the standard abundance can only be given to about ±0.001% (see table). The calculation is

Ar(Si) = (27.97693 × 0.922297) + (28.97649 × 0.046832) + (29.97377 × 0.030872) = 28.0854

The estimation of the uncertainty is complicated,[11] especially as the sample distribution is not necessarily symmetrical: the IUPAC standard relative atomic masses are quoted with estimated symmetrical uncertainties,[12] and the value for silicon is 28.0855(3). The relative standard uncertainty in this value is 1×10–5 or 10 ppm. To further reflect this natural variability, in 2010, IUPAC made the decision to list the relative atomic masses of 10 elements as an interval rather than a fixed number.[13]

جدال التسمية

The use of the name "atomic weight" has attracted a great deal of controversy among scientists.[14] Objectors to the name usually prefer the term "relative atomic mass" (not to be confused with atomic mass). The basic objection is that atomic weight is not a weight, that is the force exerted on an object in a gravitational field, measured in units of force such as the newton or poundal.[بحاجة لمصدر]

In reply, supporters of the term "atomic weight" point out (among other arguments)[14] that:

  • the name has been in continuous use for the same quantity since it was first conceptualized in 1808;[15]
  • for most of that time, atomic weights really were measured by weighing (that is by gravimetric analysis) and the name of a physical quantity should not change simply because the method of its determination has changed;
  • the term "relative atomic mass" should be reserved for the mass of a specific nuclide (or isotope), while "atomic weight" be used for the weighted mean of the atomic masses over all the atoms in the sample;
  • it is not uncommon to have misleading names of physical quantities which are retained for historical reasons, such as

It could be added that atomic weight is often not truly "atomic" either, as it does not correspond to the property of any individual atom. The same argument could be made against "relative atomic mass" used in this sense.

القيم المنشورة

قالب:Update section IUPAC publishes one formal value for each stable chemical element, called the standard atomic weight.[16][17] Any updates are published biannually (in uneven years). In 2015, the atomic weight of ytterbium was updated.[16] Per 2017, 14 atomic weights were changed, including argon changing from single number to interval value.[18][19]

The value published can have an uncertainty, like for neon: 20.1797(6), or can be an interval, like for boron: [10.806, 10.821].

Next to these 84 values, IUPAC also publishes abridged values (up to five digits per number only), and for the twelve interval values, conventional values (single number values).

Symbol Ar is a relative atomic mass, for example from a specific sample. To be specific, the standard atomic weight can be noted as Ar°(E), where (E) is the element symbol.

Abridged atomic weight

The abridged atomic weight, also published by CIAAW, is derived from the standard atomic weight reducing the numbers to five digits (five significant figures). The name does not say 'rounded'.

Interval borders are rounded downwards for the first (lowmost) border, and upwards for the upward (upmost) border. This way, the more precise original interval is fully covered.[20]

أمثلة:

  • Calcium: Ar°(Ca) = 40.078(4)Ar, abridged°(Ca) = 40.078
  • Helium: Ar°(He) = 4.002602(2)Ar, abridged°(He) = 4.0026
  • Hydrogen: Ar°(H) = [1.00784, 1.00811]Ar, abridged°(H) = [1.0078, 1.0082]

Conventional atomic weight

Fourteen chemical elements – hydrogen, lithium, boron, carbon, nitrogen, oxygen, magnesium, silicon, sulfur, chlorine, argon, bromine, thallium, and lead – have a standard atomic weight that is defined not as a single number, but as an interval. For example, hydrogen has Ar°(H) = [1.00 784, 1.00811]. This notation states that the various sources on Earth have substantially different isotopic constitutions, and uncertainties are incorporated in the two numbers. For these elements, there is not an 'Earth average' constitution, and the 'right' value is not its middle (that would be 1.007975 for hydrogen, with an uncertainty of (±0.000135) that would make it just cover the interval). However, for situations where a less precise value is acceptable, CIAAW has published a single-number conventional atomic weight that can be used for example in trade. For hydrogen, Ar, conventional°(H) = 1.008.[21]


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A formal short atomic weight

By using the abridged value, and the conventional value for the fourteen interval values, a short IUPAC-defined value (5 digits plus uncertainty) can be given for all stable elements. In many situations, and in periodic tables, this may be sufficiently detailed.[22]

Overview: formal values of the standard atomic weight[23][24]
Element (E)
Ar°(E)
نوع القيمة
Ar°(E)، مختصر
أو تقليدي
عدد الكتلة
[most stable isotope]
هيدروجين 1H Interval 1.0080±0.0002
نيتروجين 7N Interval 14.007±0.001
فلور 9F Value ± uncertainty 18.998±0.001
كالسيوم 20Ca Value ± uncertainty 40.078±0.004
تكنتيوم 43Tc (none) Most stable isotope

قائمة الأوزان الذرية

الأوزان الذرية القياسية للعناصر (IUPAC 2009–2021[ref 1])

Z الرمز الاسم Ar, standard مختصر سنة التغيير
 
1 H hydrogen - 1.0080±0.0002 2009
2 He helium - 4.0026±0.0001 1983
3 Li lithium - 6.94±0.06 2009
4 Be beryllium - 9.0122±0.0001 2013
5 B boron - 10.81±0.02 2009
6 C carbon - 12.011±0.002 2009
7 N nitrogen - 14.007±0.001 2009
8 O oxygen - 15.999±0.001 2009
9 F fluorine - 18.998±0.001 2021
10 Ne neon - 20.180±0.001 1985
11 Na sodium - 22.990±0.001 2005
12 Mg magnesium - 24.305±0.002 2011
13 Al aluminium - 26.982±0.001 2017
14 Si silicon - 28.085±0.001 2009
15 P phosphorus - 30.974±0.001 2013
16 S sulfur - 32.06±0.02 2009
17 Cl chlorine - 35.45±0.01 2009
18 Ar argon - 39.95±0.16 2017
19 K potassium - 39.098±0.001 1979
20 Ca calcium - 40.078±0.004 1983
21 Sc scandium - 44.956±0.001 2021
22 Ti titanium - 47.867±0.001 1993
23 V vanadium - 50.942±0.001 1977
24 Cr chromium - 51.996±0.001 1983
25 Mn manganese - 54.938±0.001 2017
26 Fe iron - 55.845±0.002 1993
27 Co cobalt - 58.933±0.001 2017
28 Ni nickel - 58.693±0.001 2007
29 Cu copper - 63.546±0.003 1969
30 Zn zinc - 65.38±0.02 2007
31 Ga gallium - 69.723±0.001 1987
32 Ge germanium - 72.630±0.008 2009
33 As arsenic - 74.922±0.001 2013
34 Se selenium - 78.971±0.008 2013
35 Br bromine - 79.904±0.003 2011
36 Kr krypton - 83.798±0.002 2001
37 Rb rubidium - 85.468±0.001 1969
38 Sr strontium - 87.62±0.01 1969
39 Y yttrium - 88.906±0.001 2021
40 Zr zirconium - 91.224±0.002 1983
41 Nb niobium - 92.906±0.001 2017
42 Mo molybdenum - 95.95±0.01 2013
43 Tc technetium -
44 Ru ruthenium - 101.07±0.02 1983
45 Rh rhodium - 102.91±0.01 2017
46 Pd palladium - 106.42±0.01 1979
47 Ag silver - 107.87±0.01 1985
48 Cd cadmium - 112.41±0.01 2013
49 In indium - 114.82±0.01 2011
50 Sn tin - 118.71±0.01 1983
51 Sb antimony - 121.76±0.01 1993
52 Te tellurium - 127.60±0.03 1969
53 I iodine - 126.90±0.01 1985
54 Xe xenon - 131.29±0.01 1999
55 Cs caesium - 132.91±0.01 2013
56 Ba barium - 137.33±0.01 1985
57 La lanthanum - 138.91±0.01 2005
58 Ce cerium - 140.12±0.01 1995
59 Pr praseodymium - 140.91±0.01 2017
60 Nd neodymium - 144.24±0.01 2005
61 Pm promethium -
62 Sm samarium - 150.36±0.02 2005
63 Eu europium - 151.96±0.01 1995
64 Gd gadolinium - 157.25±0.03 1969
65 Tb terbium - 158.93±0.01 2021
66 Dy dysprosium - 162.50±0.01 2001
67 Ho holmium - 164.93±0.01 2021
68 Er erbium - 167.26±0.01 1999
69 Tm thulium - 168.93±0.01 2021
70 Yb ytterbium - 173.05±0.02 2015
71 Lu lutetium - 174.97±0.01 2007
72 Hf hafnium - 178.49±0.01 2019
73 Ta tantalum - 180.95±0.01 2005
74 W tungsten - 183.84±0.01 1991
75 Re rhenium - 186.21±0.01 1973
76 Os osmium - 190.23±0.03 1991
77 Ir iridium - 192.22±0.01 2017
78 Pt platinum - 195.08±0.02 2005
79 Au gold - 196.97±0.01 2017
80 Hg mercury - 200.59±0.01 2011
81 Tl thallium - 204.38±0.01 2009
82 Pb lead - 207.2±1.1 2020
83 Bi bismuth - 208.98±0.01 2005
84 Po polonium -
85 At astatine -
86 Rn radon -
87 Fr francium -
88 Ra radium -
89 Ac actinium -
90 Th thorium - 232.04±0.01 2013
91 Pa protactinium - 231.04±0.01 2017
92 U uranium - 238.03±0.01 1999
93 Np neptunium -
94 Pu plutonium -
95 Am americium -
96 Cm curium -
97 Bk berkelium -
98 Cf californium -
99 Es einsteinium -
100 Fm fermium -
101 Md mendelevium -
102 No nobelium -
103 Lr lawrencium -
104 Rf rutherfordium -
105 Db dubnium -
106 Sg seaborgium -
107 Bh bohrium -
108 Hs hassium -
109 Mt meitnerium -
110 Ds darmstadtium -
111 Rg roentgenium -
112 Cn copernicium -
113 Nh nihonium -
114 Fl flerovium -
115 Mc moscovium -
116 Lv livermorium -
117 Ts tennessine -
118 Og oganesson -
  1. ^
      (This list:  view • edit )
    CIAAW may publish changes to atomic weights (including its precision and derived values). Since 1947, any update this is done in odd years nominally; the actual date of publication may be some time later.
    • 2009 (introducing interval notation; Ge):
    "Atomic weights of the elements 2009 (IUPAC Technical Report)". Pure Appl. Chem. 83 (2): 359–396. 12 December 2010. doi:10.1351/PAC-REP-10-09-14.
    • 2011 (interval for Br, Mg):
    قالب:CIAAW2011
    • 2013 (all elements listed):
    Meija, Juris; et al. (2016). "Atomic weights of the elements 2013 (IUPAC Technical Report)". Pure and Applied Chemistry. 88 (3): 265–91. doi:10.1515/pac-2015-0305.
    • 2015 (ytterbium changed):
    قالب:CIAAW2015
    • 2017 (14 values changed):
    "Standard atomic weights of 14 chemical elements revised". CIAAW. 2018-06-05.
    * "2020" is an inconsistent year for change publication: CIAAW maintains that only odd years, changes are publicised.
    • 2021 (all elements listed); (4 values changed; introduced new symbol; merge "conventional" into "abridged" columns; change uncertainty notation (use "±")
    Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry (in الإنجليزية). doi:10.1515/pac-2019-0603. ISSN 1365-3075.
    Uncertainty handling

    About notation and handling of the uncertainty in the values, including those in [ ] range values:

    المراجع اللاغية
    See also: {{Isotopes table/references}}


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في الجدول الدوري

المجموعة 1 2   3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
الهيدروجين
والفلزات القلوية
الفلزات الأرضية القلوية Pnicto­gens Chal­co­gens Halo­gens Noble
gases
الدورة

1

Hydro­gen
1
He­lium
2
2
Lith­ium
3
Beryl­lium
4
Boron
5
Carbon
6
Nitro­gen
7
Oxy­gen
8
Fluor­ine
9
Neon
10
3
So­dium
11
Magne­sium
12
Alumin­ium
13
Sili­con
14
Phos­phorus
15
Sulfur
16
Chlor­ine
17
Argon
18
4
Potas­sium
19
Cal­cium
20
Scan­dium
21
Tita­nium
22
Vana­dium
23
Chrom­ium
24
Manga­nese
25
Iron
26
Cobalt
27
Nickel
28
Copper
29
Zinc
30
Gallium
31
Germa­nium
32
Arsenic
33
Sele­nium
34
Bromine
35
Kryp­ton
36
5
Rubid­ium
37
Stront­ium
38
Yttrium
39
Zirco­nium
40
Nio­bium
41
Molyb­denum
42
Tech­netium
43
Ruthe­nium
44
Rho­dium
45
Pallad­ium
46
Silver
47
Cad­mium
48
Indium
49
Tin
50
Anti­mony
51
Tellur­ium
52
Iodine
53
Xenon
54
6
Cae­sium
55
Barium
56
Asterisks one.svg
Lute­tium
71
Haf­nium
72
Tanta­lum
73
Tung­sten
74
Rhe­nium
75
Os­mium
76
Iridium
77
Plat­inum
78
Gold
79
Mer­cury
80
Thallium
81
Lead
82
Bis­muth
83
Polo­nium
84
Asta­tine
85
Radon
86
7
Fran­cium
87
Ra­dium
88
Asterisks one.svg
Lawren­cium
103
Ruther­fordium
104
Dub­nium
105
Sea­borgium
106
Bohr­ium
107
Has­sium
108
Meit­nerium
109
Darm­stadtium
110
Roent­genium
111
Coper­nicium
112
Unun­trium
113
Flerov­ium
114
Unun­pentium
115
Liver­morium
116
Unun­septium
117
Unun­octium
118
Asterisks one.svg
Lan­thanum
57
Cerium
58
Praseo­dymium
59
Neo­dymium
60
Prome­thium
61
Sama­rium
62
Europ­ium
63
Gadolin­ium
64
Ter­bium
65
Dyspro­sium
66
Hol­mium
67
Erbium
68
Thulium
69
Ytter­bium
70
 
Asterisks one.svg
Actin­ium
89
Thor­ium
90
Protac­tinium
91
Ura­nium
92
Neptu­nium
93
Pluto­nium
94
Ameri­cium
95
Curium
96
Berkel­ium
97
Califor­nium
98
Einstei­nium
99
Fer­mium
100
Mende­levium
101
Nobel­ium
102

انظر أيضاً

المراجع

  1. ^ Meija, J.; Coplen, T. B. (2016). "Atomic weights of the elements 2013 (IUPAC Technical Report)". Pure and Applied Chemistry. 88 (3): 265–91. doi:10.1515/pac-2015-0305. {{cite journal}}: Unknown parameter |displayauthors= ignored (|display-authors= suggested) (help)
  2. ^ أ ب "IUPAC Goldbook". Compendium of Chemical Terminology. doi:10.1351/goldbook.S05907. Retrieved 12 July 2019. standard atomic weights: Recommended values of relative atomic masses of the elements revised biennially by the IUPAC Commission on Atomic Weights and Isotopic Abundances and applicable to elements in any normal sample with a high level of confidence. A normal sample is any reasonably possible source of the element or its compounds in commerce for industry and science and has not been subject to significant modification of isotopic composition within a geologically brief period.
  3. ^ Wieser, M. E (2006). "Atomic weights of the elements 2005 (IUPAC Technical Report)" (PDF). Pure and Applied Chemistry. 78 (11): 2051–2066. doi:10.1351/pac200678112051. S2CID 94552853.
  4. ^ Lodders, K. (2008). "The solar argon abundance". Astrophysical Journal. 674 (1): 607–611. arXiv:0710.4523. Bibcode:2008ApJ...674..607L. doi:10.1086/524725. S2CID 59150678.
  5. ^ Cameron, A. G. W. (1973). "Elemental and isotopic abundances of the volatile elements in the outer planets". Space Science Reviews. 14 (3–4): 392–400. Bibcode:1973SSRv...14..392C. doi:10.1007/BF00214750. S2CID 119861943.
  6. ^ This can be determined from the preceding figures per the definition of atomic weight and WP:CALC
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  8. ^ أ ب قالب:AME 2003
  9. ^ أ ب قالب:AtWt TICE 1997
  10. ^ Coplen, T. B. (2002), "Isotopic Abundance Variations of Selected Elements", Pure and Applied Chemistry 74 (10): 1987–2017, doi:10.1351/pac200274101987, http://www.iupac.org/publications/pac/2002/pdf/7410x1987.pdf 
  11. ^ Meija, Juris; Mester, Zoltán (2008). "Uncertainty propagation of atomic weight measurement results". Metrologia. 45 (1): 53–62. Bibcode:2008Metro..45...53M. doi:10.1088/0026-1394/45/1/008. S2CID 122229901.
  12. ^ Holden, Norman E. (2004). "Atomic Weights and the International Committee—A Historical Review". Chemistry International. 26 (1): 4–7.
  13. ^ "IUPAC – International Union of Pure and Applied Chemistry: Atomic Weights of Ten Chemical Elements About to Change". Archived from the original on 2020-07-28. Retrieved 2019-07-12.
  14. ^ أ ب de Bièvre, Paul; Peiser, H. Steffen (1992). "'Atomic Weight' — The Name, Its History, Definition, and Units" (PDF). Pure and Applied Chemistry. 64 (10): 1535–43. doi:10.1351/pac199264101535.
  15. ^ Dalton, John (1808). A New System of Chemical Philosophy. Manchester.
  16. ^ أ ب "Standard Atomic Weights 2015". Commission on Isotopic Abundances and Atomic Weights. 12 October 2015. Retrieved 18 February 2017.
  17. ^ Meija 2016, Table 1.
  18. ^ "Standard atomic weights of 14 chemical elements revised". CIAAW. 2018-06-05. Retrieved 2019-02-02.
  19. ^ "Standard Atomic Weights of 14 Chemical Elements Revised". Chemistry International. 40 (4): 23–24. 2018. doi:10.1515/ci-2018-0409. ISSN 0193-6484.
  20. ^ Meija 2016, Table 2.
  21. ^ Meija 2016, Table 3.
  22. ^ Meija 2016, Tables 2 and 3.
  23. ^ أ ب Meija, Juris; et al. (2016). "Atomic weights of the elements 2013 (IUPAC Technical Report)". Pure and Applied Chemistry. 88 (3): 265–91. doi:10.1515/pac-2015-0305.
  24. ^ أ ب Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry (in الإنجليزية). doi:10.1515/pac-2019-0603. ISSN 1365-3075.

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